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De values for HTO in the Opalinus Clay cluster within a small range and are almost identical for all three siting regions (Fig. 5‑51).
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As a result of differences in porewater ionic strength, De for chloride shows site-specific differences, with lowest values in JO.
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The geometric factor G can be correlated to the clay-mineral content both for HTO and for Cl (Fig. 5-53). As (accessible) porosity is also correlated with the clay-mineral content (Fig. 5‑11), De of HTO or Cl can be estimated from clay-mineral contents from Base Lias Group up to the Malm Group. Outlier lithologies can be identified and relate to rocks with special texture and pore architecture (pore-size distribution, pore connectivity) probably related to distinct diagenetic features, notably the Rietheim Member rich in organic matter («Posidonienschiefer»).
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The Dogger Group above Opalinus Clay and the Lias Group below the Opalinus Clay show more variability of diffusion properties, because of the more variable lithology (Fig. 5‑51).
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For the Opalinus Clay, diffusion coefficients determined on small drill core samples in the laboratory match well with those derived from field-scale diffusion experiments in the Mont Terri rock laboratory (Fig. 5‑54).
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The anisotropy factor for diffusion in the Opalinus Clay (values parallel to bedding compared to values perpendicular to bedding) is in the order of 3 – 6.
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Using laboratory diffusion coefficients (adjusted for increased temperature at greater depths) in simulations of the tracer profiles leads to good matches with the tracer profiles for plausible evolution times.
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No obvious scale dependence of diffusion properties of the Opalinus Clay between the lab, underground rock laboratory and formation scale was detected; local variations can be related to differences in the porosity or the clay-mineral content and the specific microstructure of samples from certain layers.